2-[4-Chloro-3-(4-ethoxybenzyl)phenyl]-1,3-dithiane
نویسندگان
چکیده
In the title compound, C(19)H(21)ClOS(2), the dithiane ring adopts a chair conformation. The dihedral angle between the benzene rings is 87.88 (4)°. In the crystal, inversion dimmers linked by pairs of C-H⋯O inter-actions occur.
منابع مشابه
4-(5-tert-Butyl-1,3-dithian-2-yl)-5-chloro-2-phenyl-1,3-oxazole
In the title mol-ecule, C(17)H(20)ClNOS(2), the phenyl and oxazole rings are nearly coplanar with an average deviation of 0.022 Å from the mean plane (M). The 1,3-dithiane ring adopts a chair conformation and is twisted in such a way that the C-C(Bu) fragment lies in M (deviations are 0.031 and 0.010 Å, respectively, for the two C atoms).
متن کاملSynthesis of 5-hydroxy-2,3,4,5-tetrahydro-[1H]-2-benzazepin-4-ones: selective antagonists of muscarinic (M3) receptors.
Two approaches to tetrahydro-[1H]-2-benzazepin-4-ones of interest as potentially selective, muscarinic (M(3)) receptor antagonists have been developed. Base promoted addition of 2-(tert-butoxycarbonylamino)methyl-1,3-dithiane with 2-(tert-butyldimethylsiloxymethyl)benzyl chloride gave the corresponding 2,2-dialkylated 1,3-dithiane which was taken through to the dithiane derivative of the parent...
متن کامل2-(4-Nitrophenyl)-1,3-dithiane
The nitro group in the title compound, C(10)H(11)NO(2)S(2), is almost coplanar with the benzene ring, making a dihedral angle of 3.42 (8)°. The 1,3-dithiane ring adopts a chair conformation. The crystal structure is stabilized by inter-molecular C-H⋯O and C-H⋯π [C⋯Cg = 3.4972 (10) Å] inter-actions.
متن کامل2-Methyl-2-(3-nitrophenyl)-1,3-dithiane
The title compound, C(11)H(13)NO(2)S(2), contains a 1,3-dithiane ring in an almost ideal chair conformation with the following puckering parameters: Q = 0.7252 (15) Å, θ = 6.71 (13) and ϕ = 50.4 (11)°. The benzene ring occupies an axial position at the dithiane ring. The nitro group is almost coplanar with the benzene ring [O-N-C-C = -3.2 (2)°]. The mol-ecule has an L-shape with a C-C-C-C torsi...
متن کامل4-(4-Ethoxybenzyl)-1,3-oxazolidin-2-one
In the title compound, C(12)H(15)NO(3), the ethoxy-benzyl ring plane forms a dihedral angle of 60.3 (4)° with the mean plane of the oxazolidine ring. The mol-ecules are linked through N-H⋯O hydrogen bonds into a chain running in the b direction.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010